The Spanish prime minister has outlined plans to remove Catalonia's leaders and take control of the separatist region.
Speaking after an emergency cabinet meeting on Saturday, Mariano Rajoy stopped short of dissolving the region's parliament but put forward plans for elections in the region.
The measures must now be approved by Spain's Senate in the next few days.
The plans come almost three weeks after Catalonia held a disputed independence referendum.
Spain's supreme court had declared the vote illegal and said it violated the constitution, which describes the country as indivisible.
Catalan leader Carles Puigdemont has ignored pleas from the national government to withdraw the independence bid.
Mr Rajoy said the government had no choice but to push to impose direct rule, arguing that the Catalan government's actions were "contrary to the law and seeking confrontation".
This will be via Article 155 of Spain's constitution, which allows it to impose direct rule in a crisis on any of the country's semi-autonomous regions.
Spain's Senate will vote within the week, Mr Rajoy said at a press conference. He said it was "not our wish, it was not our intention" to trigger the article.
Spanish law dictates that elections must be held within six months of Article 155 being triggered, but Mr Rajoy said it was imperative that the vote be held much sooner.
How did we get here?
Catalonia's regional government held a referendum on 1 October to ask residents of the region if they wanted to break away from Spain.
Of the 43% of Catalans said to have taken part, 90% voted in favour of independence. But many anti-independence supporters boycotted the ballot, arguing it was not valid.
Mr Puigdemont and other regional leaders then signed a declaration of independence, but immediately suspended it in order to allow for talks.
He then defied two deadlines set by the national government to clarify Catalonia's position, and the government announced it would pursue Article 155.
What is Article 155?
Article 155 of the Spanish constitution allows the national government to impose direct rule over Spain's semi-autonomous regions in the event of a crisis. It has never before been invoked in democratic Spain.
It says that if a region's government "acts in a way that seriously threatens the general interest of Spain", Madrid can "take necessary measures to oblige it forcibly to comply".
Catalonia currently enjoys significant autonomy from Spain, including control over its own policing, education and healthcare.
Mr Rajoy's conservative Popular Party (PP) holds a majority in the Senate, meaning the proposals are likely to pass.
What are the economic arguments?
Catalonia accounts for about a fifth of Spain's economic output, and supporters of independence say the region contributes too much to the national economy.
Opponents argue that Catalonia is stronger as a part of Spain, and that breaking away would lead to economic disaster for the country as a whole.
Nearly 1,200 companies based in Catalonia have re-registered in other parts of Spain since the referendum, hoping to minimise instability, according to the AFP news agency.
And Spain this week cut its national growth forecast for 2018 from 2.6% to 2.3%, blaming uncertainty over the future of Catalan independence.
Could Spain's steps backfire?
James Badcock, BBC News, Madrid
There are plenty of reasons to doubt that such a strategy would provide a clear solution to the crisis.
The far-left CUP party has suggested that it would boycott any election imposed on the region. Other pro-independence forces might do the same. Massive street protests against any form of direct rule from Madrid can also be expected.
Mr Puigdemont has promised to call a formal vote on independence in Catalonia's parliament if Article 155 is invoked. If such a declaration were approved, the pro-independence forces could style the ballot as the election of a constituent assembly for a new republic, the next stage laid down in the pro-independence road map.
Assuming the participation of all parties, voters would be bound to interpret the election as a de facto vote on independence. If a separatist majority emerged once again, it is hard to see how the conflict could be considered closed.